A Review on Luminescent Rare Earth Complexes
International Research Journal of Pure and Applied Chemistry,
Page 69-77
DOI:
10.9734/irjpac/2021/v22i330397
Abstract
At present, rare earth elements are widely used in various industries. In this paper, luminescent rare earth complexes are taken as a starting point to explore the luminescence principles of several important rare earth elements. The commonly used synthesis methods of luminescent rare earth complexes in recent year are also summarized, mainly including co-precipitation method, high temperature solid phase method, sol-gel method and hydrothermal synthesis method. And prospects for the future research on luminescent rare earth complexes are made.
Keywords:
- Rare earth complexes
- luminescence materials
- synthesis method
- light emitting diodes.
How to Cite
Shen, Q. S., Xu, L., Jiang, Y., & Zhang, Y. (2021). A Review on Luminescent Rare Earth Complexes. International Research Journal of Pure and Applied Chemistry, 22(3), 69-77. https://doi.org/10.9734/irjpac/2021/v22i330397
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Ou ZH, Ge YQ. Research progress of rare earth complex luminescent materials for near ultraviolet white LED. Guangdong Chemical Industry. Chinese. 2021;48(7):67-68.
Wu DL. Synthesis, luminescent properties of the rare earth complexes based on the bifunctional ligand of carboxyl and β-diketo. Master Dissertation, Zhejiang Normal University, China; 2018.
Guo CF. Progress on luminescent materials of rare-earth Europium complexes. Guangzhou Chemistry. Chinese. 2018;43(5):68-72.
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Sun J, Xu SC, Song WR, Ma MY, Li MF, Ji CY, Meng QW, Zhang K, Wang ZJ. Luminescence property and mechanism of yellow-green long persistent phosphor Ba2B2O5:Ce3+,Dy3+. Journal of the Chinese ceramic society. Chinese. 2017;45(10):1454-1458.
Matsuzawa T, Aoki Y, Takeuchi N, Murayama Y. A new long phosphorescent phosphor with high brightness, SrAl2O4:Eu2+, Dy3+. Journal of the Electrochemical Society. 1996;143(8):2670-2673.
Chen ZB. Synthesis, structures and luminescent properties of lanthanide/lanthanide-transition metal coordination complexes. Master Dissertation, Zhejiang Normal University, China; 2020.
Zhu D. Synthesis and properties of rare earth ion doped Ba3Y4O9 fluorescent materials. Master Dissertation, University of Jinan. China; 2020.
Liu Y. Fabrication and properties of rare earth ions doped CaF2 transparent ceramics. Master Dissertation, Jiangsu University. China; 2020.
Akca S, Oglakci M, Portakal ZG, Kucuk N, Bakr M, Topaksu M, Can N. Thermoluminescence analysis of beta irradiated ZnB2O4:Pr3+ phosphors synthesized by a wet-chemical method. Radiation Physics and Chemistry. 2019;160:105-111.
Chen SL, Hou YK, Wang H, Zhao Z, Zhang YQ, Yang JY, Huang XW. Enhanced thermal stability of Ce0.33Zr0.55(LaNdY)0.12O2 mixed oxides prepared by sulfate-aided coprecipitation method. Journal of Rare Earths. 2021;39(5):587-595.
Nie K, Ma XX, Lin PL, Kumar N, Wang LX, Mei LF. Synthesis and luminescence properties of apatite-type red-emitting Ba2La8(GeO4)6O2:Eu3+ phosphor. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.10.019
Wang Y, Zhao BK, Deng B, Chen SS, Liu YY, Wang GD, Yu RJ. Spectral properties and Judd-Ofelt analysis of novel red phosphors Gd2InSbO7:Eu3+ with high color purity for white LEDs. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.08.002
Xia JX. Preparation and properties of red fluorescence powder Zn2SiO4:Eu3+ by solid state reaction. Guangdong Chemical Industry. Chinese. 2014;41(13):1-3.
Zhang Q. Preparation, structures and luminescent properties of luminescent composites based on rare earth complexes. Ph.D. Dissertation, Jilin University. China; 2019.
Guo H, Dong N, Yin M, Zhang WP, Lou LR, Xia SD. Visible upconversion in rare earth ion-doped Gd2O3 nanocrystals. Journal of Physical Chemistry B. 2004;108(50):19205–19209.
Lim CS, Aleksandrovsky A, Molokeev M, Oreshonkov A, Atuchin V. Microwave sol-gel synthesis and upconversion photoluminescence properties of CaGd2(WO4)4:Er3+/Yb3+ phosphors with incommensurately modulated structure. Journal of Solid State Chemistry. 2015;228:160-166.
Tang LL, Meng QY, Sun WJ, Lü SC. Preparation and temperature sensing behavior of NaY(MoO4)2:Pr3+, Tb3+ phosphors. Journal of Luminescence; 2020.
Available:https://doi.org/10.1016/j.jlumin.2020.117728
Yu XF, Yuan DW, Mi XY. Hydrothermal synthesis and luminescent properties of Ca3(PO4)2:Dy3+ white-emitting phosphors. Journal of Alloys and Compounds; 2020.
Available:https://doi.org/10.1016/j.jallcom.2020.157585
Yu LY. Synthesis and luminescence property of rare earth fluoride luminescent materials based on energy transfer. Master Dissertation, Changchun University of Science and Technology. China; 2020.
Zhang YY, Li Y, Zhang J, Guo W, Zhang SS, Su HQ, Li XJ, Yuan ZB. Simultaneous morphology manipulation, upconversion luminescence enhancement and the photoelectric effect of NaGd0.78-xZrxF4:Yb3+/Er3+ nanophosphors. Journal of Luminescence. 2019;207:443-453.
Gnanam S, Gajendiran J, Ramana Ramya J, Ramachandran K, Gokul Raj S. Glycine-assisted hydrothermal synthesis of pure and europium doped CeO2 nanoparticles and their structural, optical, photoluminescence, photocatalytic and antibacterial properties. Chemical Physics Letters; 2020.
Available:https://doi.org/10.1016/j.cplett.2020.138217
Phuruangrat A, Thongtem T, Thongtem S. Hydrothermal synthesis and characterization of Dy-doped CeVO4 nanorods used for photodegradation of methylene blue and rhodamine B. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.11.005
Hao S, Wei YD, Liu XR. La2Ti6O15-CeTi21O38-PbTiO3 ceramics formed in gaseous penetration of La-Ce into PbTiO3 and their electric properties. Science in China(B). 2003;46(3):313-319.
Zhu D, Li JK, Duan GB, Liu ZM. Progress in preparation of Ba-Gd(Y)-O fluorescent materials. Journal of University of Jinan(Science and Technology). Chinese. 2019;33(1):1-7.
Zhang SQ. Self-propagating high-temperature synthesis-new technology for manufacturing inorganic materials. Journal of Materials Engineering. Chinese. 1993;(7):41-44.
Chen YF, Ye H, Wang Q, Cheng J, Guo J, Li P. Preparation of upconversion luminescent NaYF4:Yb, Tm nanoparticles by impinging stream method. Journal of Wuhan Institute of Technology. Chinese. 2020;42(6):604-609.
Zhang DD. Design and preparation of different structures of schiff base type polymer-rare earth complexes and Study on the photoluminescence properties of the complexes. Ph.D. Dissertation, North University of China. China; 2018.
Li JY. Rare earth luminescent materials and their applications. Beijing: Chemical Industry Press. Chinese. 2003;192-196.
Huang CH. Rare earth coordination chemistry. Beijing: Science Press. Chinese. 1997;372-380.
Fu YL. The synthesize and property study of rare earth luminesence complexes and organic electronic material. Master Dissertation, Beijing University of Chemical Technology. China; 2008.
Li ZY. Preparation and properties of efficient stable and tunable rare earth UV enhanced thin films. Master Dissertation, Hefei University of Technology. China; 2019.
Qian GD, Liu Y, Wang ZY, Qiu JR, Fan XP, Hong ZL, Wang MQ. Double rare earth organic complex doped temperature-sensitive sensing luminescent material and preparation method. CN 1693416 A. China; 2005.
Li Z. Synthesis and luminescence properties of chiral rare earth complexes. Master Dissertation, Jinan University. China; 2010.
Chen A, Liu ZH. Progress and development direction in research of luminescent rare earth complex material. Guangdong Chemical Industry. Chinese; 2017;44(20):100-101.
Xu XJ. Development of rare earth luminescent materials and their applications. Rare Earth Information. Chinese. 2003;(12):7-10.
Hong GY. Research progress of rare earth luminescent materials. Journal of Synthetic Crystals. Chinese. 2015;44(10):2641-2651.
Zhang AQ. Design, synthesis and luminescent properties of rare earth polymer phosphor in white light LED. Ph.D. Dissertation, Taiyuan University of Technology. China; 2012.
Pan QL. Design, synthesis and property of polymer phosphors in white light emitting diode(WLED). Master Dissertation, Taiyuan University of Technology. China; 2012.
Zhang B, Ning YK, Cao F, Yang HP. Current situationof worldwide rare earth resources. Multipurpose Utilization of Mineral Resources. Chinese. 2018;(4):7-12.
Li ZM, Liu YL, Li P, Zhang L, Zhang AW, Lin DL. Analysis of global rare earth supply trend. Chinese Rare Earths. Chinese. 2016;37(6):146-154.
Shen LJ, Qiao X, Wang ZZ. The status quo and prospects of rare earth luminescent materials technology. Rare Earth Information. Chinese. 2019;(4):10-14.
Zhu CC. Study on the synthesis, luminescent and magnetic properties of the lanthanide complexes based on β-diketone ligands. Master Dissertation, Zhengzhou University of Light Industry, China; 2018.
Zhou BL, Li ZX, Zhao YQ. Current status of world rare earths market and countermeasures for its industry development. Journal of the Chinese Society of Rare Earths. Chinese. 2016;34(3):257-264.
Wang CM, Liu YZ, Zhao LS, Zhao N, Feng ZY, Huang XW. Current situation and development tendency on rare materials and its green preparation technologies in China. Materials China. Chinese. 2018;37(11):841-847.
Zhao XJ. Synthesis and luminescent properties of UV resistant Eu-polymer phosphors. Ph.D. Dissertation, Taiyuan University of Technology. China; 2017.
Ou ZH, Ge YQ. Research progress of rare earth complex luminescent materials for near ultraviolet white LED. Guangdong Chemical Industry. Chinese. 2021;48(7):67-68.
Wu DL. Synthesis, luminescent properties of the rare earth complexes based on the bifunctional ligand of carboxyl and β-diketo. Master Dissertation, Zhejiang Normal University, China; 2018.
Guo CF. Progress on luminescent materials of rare-earth Europium complexes. Guangzhou Chemistry. Chinese. 2018;43(5):68-72.
Ji CH, Zhang P, Han PF. Progress of study on red fluorescence europium complexes. Chemistry Bulletin. Chinese. 2008;71(10):746-754.
Fang PY, Huo PH, Liu ZW, Huang YY, Bian ZQ, Huang CH. Research progress of d-f transition based luminescent rare earth complexes. Journal of the chinese society of rare earths. Chinese. 2021;39(1):58-76.
Zhao ZF, Wang LD, Zhan G, Liu ZW, Bian AQ, Huang CH. d-f transition light-emitting rare earth complex and its organic light-emitting diode. China Rare Earth Society 2020 annual conference and Jiangxi (Ganzhou) rare earth resources green development and efficient utilization conference. China; 2020.
Tang L. Study on preparation and luminescence property of YVO4:Eu3+ and YVO4:Tb3+ nanoparticles. New Chemical Materials. Chinese. 2020;48(8):165-168+173.
Sun J, Xu SC, Song WR, Ma MY, Li MF, Ji CY, Meng QW, Zhang K, Wang ZJ. Luminescence property and mechanism of yellow-green long persistent phosphor Ba2B2O5:Ce3+,Dy3+. Journal of the Chinese ceramic society. Chinese. 2017;45(10):1454-1458.
Matsuzawa T, Aoki Y, Takeuchi N, Murayama Y. A new long phosphorescent phosphor with high brightness, SrAl2O4:Eu2+, Dy3+. Journal of the Electrochemical Society. 1996;143(8):2670-2673.
Chen ZB. Synthesis, structures and luminescent properties of lanthanide/lanthanide-transition metal coordination complexes. Master Dissertation, Zhejiang Normal University, China; 2020.
Zhu D. Synthesis and properties of rare earth ion doped Ba3Y4O9 fluorescent materials. Master Dissertation, University of Jinan. China; 2020.
Liu Y. Fabrication and properties of rare earth ions doped CaF2 transparent ceramics. Master Dissertation, Jiangsu University. China; 2020.
Akca S, Oglakci M, Portakal ZG, Kucuk N, Bakr M, Topaksu M, Can N. Thermoluminescence analysis of beta irradiated ZnB2O4:Pr3+ phosphors synthesized by a wet-chemical method. Radiation Physics and Chemistry. 2019;160:105-111.
Chen SL, Hou YK, Wang H, Zhao Z, Zhang YQ, Yang JY, Huang XW. Enhanced thermal stability of Ce0.33Zr0.55(LaNdY)0.12O2 mixed oxides prepared by sulfate-aided coprecipitation method. Journal of Rare Earths. 2021;39(5):587-595.
Nie K, Ma XX, Lin PL, Kumar N, Wang LX, Mei LF. Synthesis and luminescence properties of apatite-type red-emitting Ba2La8(GeO4)6O2:Eu3+ phosphor. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.10.019
Wang Y, Zhao BK, Deng B, Chen SS, Liu YY, Wang GD, Yu RJ. Spectral properties and Judd-Ofelt analysis of novel red phosphors Gd2InSbO7:Eu3+ with high color purity for white LEDs. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.08.002
Xia JX. Preparation and properties of red fluorescence powder Zn2SiO4:Eu3+ by solid state reaction. Guangdong Chemical Industry. Chinese. 2014;41(13):1-3.
Zhang Q. Preparation, structures and luminescent properties of luminescent composites based on rare earth complexes. Ph.D. Dissertation, Jilin University. China; 2019.
Guo H, Dong N, Yin M, Zhang WP, Lou LR, Xia SD. Visible upconversion in rare earth ion-doped Gd2O3 nanocrystals. Journal of Physical Chemistry B. 2004;108(50):19205–19209.
Lim CS, Aleksandrovsky A, Molokeev M, Oreshonkov A, Atuchin V. Microwave sol-gel synthesis and upconversion photoluminescence properties of CaGd2(WO4)4:Er3+/Yb3+ phosphors with incommensurately modulated structure. Journal of Solid State Chemistry. 2015;228:160-166.
Tang LL, Meng QY, Sun WJ, Lü SC. Preparation and temperature sensing behavior of NaY(MoO4)2:Pr3+, Tb3+ phosphors. Journal of Luminescence; 2020.
Available:https://doi.org/10.1016/j.jlumin.2020.117728
Yu XF, Yuan DW, Mi XY. Hydrothermal synthesis and luminescent properties of Ca3(PO4)2:Dy3+ white-emitting phosphors. Journal of Alloys and Compounds; 2020.
Available:https://doi.org/10.1016/j.jallcom.2020.157585
Yu LY. Synthesis and luminescence property of rare earth fluoride luminescent materials based on energy transfer. Master Dissertation, Changchun University of Science and Technology. China; 2020.
Zhang YY, Li Y, Zhang J, Guo W, Zhang SS, Su HQ, Li XJ, Yuan ZB. Simultaneous morphology manipulation, upconversion luminescence enhancement and the photoelectric effect of NaGd0.78-xZrxF4:Yb3+/Er3+ nanophosphors. Journal of Luminescence. 2019;207:443-453.
Gnanam S, Gajendiran J, Ramana Ramya J, Ramachandran K, Gokul Raj S. Glycine-assisted hydrothermal synthesis of pure and europium doped CeO2 nanoparticles and their structural, optical, photoluminescence, photocatalytic and antibacterial properties. Chemical Physics Letters; 2020.
Available:https://doi.org/10.1016/j.cplett.2020.138217
Phuruangrat A, Thongtem T, Thongtem S. Hydrothermal synthesis and characterization of Dy-doped CeVO4 nanorods used for photodegradation of methylene blue and rhodamine B. Journal of Rare Earths; 2020.
Available:https://doi.org/10.1016/j.jre.2020.11.005
Hao S, Wei YD, Liu XR. La2Ti6O15-CeTi21O38-PbTiO3 ceramics formed in gaseous penetration of La-Ce into PbTiO3 and their electric properties. Science in China(B). 2003;46(3):313-319.
Zhu D, Li JK, Duan GB, Liu ZM. Progress in preparation of Ba-Gd(Y)-O fluorescent materials. Journal of University of Jinan(Science and Technology). Chinese. 2019;33(1):1-7.
Zhang SQ. Self-propagating high-temperature synthesis-new technology for manufacturing inorganic materials. Journal of Materials Engineering. Chinese. 1993;(7):41-44.
Chen YF, Ye H, Wang Q, Cheng J, Guo J, Li P. Preparation of upconversion luminescent NaYF4:Yb, Tm nanoparticles by impinging stream method. Journal of Wuhan Institute of Technology. Chinese. 2020;42(6):604-609.
Zhang DD. Design and preparation of different structures of schiff base type polymer-rare earth complexes and Study on the photoluminescence properties of the complexes. Ph.D. Dissertation, North University of China. China; 2018.
Li JY. Rare earth luminescent materials and their applications. Beijing: Chemical Industry Press. Chinese. 2003;192-196.
Huang CH. Rare earth coordination chemistry. Beijing: Science Press. Chinese. 1997;372-380.
Fu YL. The synthesize and property study of rare earth luminesence complexes and organic electronic material. Master Dissertation, Beijing University of Chemical Technology. China; 2008.
Li ZY. Preparation and properties of efficient stable and tunable rare earth UV enhanced thin films. Master Dissertation, Hefei University of Technology. China; 2019.
Qian GD, Liu Y, Wang ZY, Qiu JR, Fan XP, Hong ZL, Wang MQ. Double rare earth organic complex doped temperature-sensitive sensing luminescent material and preparation method. CN 1693416 A. China; 2005.
Li Z. Synthesis and luminescence properties of chiral rare earth complexes. Master Dissertation, Jinan University. China; 2010.
Chen A, Liu ZH. Progress and development direction in research of luminescent rare earth complex material. Guangdong Chemical Industry. Chinese; 2017;44(20):100-101.
Xu XJ. Development of rare earth luminescent materials and their applications. Rare Earth Information. Chinese. 2003;(12):7-10.
Hong GY. Research progress of rare earth luminescent materials. Journal of Synthetic Crystals. Chinese. 2015;44(10):2641-2651.
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